{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2 N 1,S)methyl]-6-hydroxyphenolato-κO 1}(triphenylphosphine-κP)nickel(II) chloride
نویسندگان
چکیده
The deprotonated Schiff base ligand in the title compound, [Ni(C(8)H(8)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hy-droxy group forms an intra-molecular O-H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
منابع مشابه
(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-κ2 N 1,S]methyl}phenolato-κO 1)(triphenylphosphane-κP)nickel(II) chloride
The deprotonated Schiff base ligand in the title salt, [Ni(C(9)H(10)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hy-droxy group forms an intra-molecular O-H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bond...
متن کامل(Dithiobenzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-κN 2)borato](triphenylphosphine-κP)ruthenium(II)
Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a...
متن کامل{2-[(2-Acetylhydrazin-1-ylidene)methyl-κ2 N 1,O]-6-methoxyphenolato-κO 1}(nitrato-κO)copper(II) monohydrate
In the title complex, [Cu(C(10)H(11)N(2)O(3))(NO(3))]·H(2)O, prepared from the Schiff base N'-(3-meth-oxy-2-oxidobenzyl-idene)-acetohydrazide, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and one O atom from a nitrate group in a distorted square-planar geometry. The Cu(II) atom has a weak inter-action with another O atom of the nitrate group. The two O atoms of t...
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There are two independent mol-ecules with similar configurations in the title complex, [Mo(C(3)H(6)NS)(C(5)H(4)NS)(C(18)H(15)P)(CO)(2)]. The geometry around the metal atom is that of a capped octa-hedron. The thio-cabamoyl and pyridine-2-thiol-ate ligands coordinate to the molybdenum metal center through the C and S atoms, and N and S atoms, respectively. NMR, IR and MS analyses are in agreemen...
متن کاملBis{2-[3-(hydroxyimino-κN)butan-2-ylidene]-N-methylhydrazinecarbothioamide-κ2 N 2,S}nickel(II) dichloride
The asymmetric unit of the title compound, [Ni(C(6)H(12)N(4)OS)(2)]Cl(2), contains two independent Ni(II) complex cations and four chloride anions. Each Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N-H⋯Cl and O-H⋯Cl hydroge...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010